Category:Exchange-correlation functionals

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In the Kohn-Sham (KS) formulation of density-functional theory (DFT)[1][2], the total energy is given by

where the terms on the right-hand side represent the non-interacting kinetic energy of the electrons, the electrons-nuclei attraction energy, the classical Coulomb electron-electron repulsive energy, the exchange-correlation energy, and the nuclei-nuclei repulsion energy, respectively. The KS orbitals and the electronic density that are used to evaluate are obtained by solving self-consistently the KS equations

The only terms in and in the KS equations that are not known exactly are the exchange-correlation energy functional and potential . Therefore, the accuracy of the calculated properties depends strongly on the approximations used for and .

Several hundreds of approximations for the exchange and correlation have been proposed[3]. They can be classified into families: the local density approximation (LDA), generalized gradient approximation (GGA), meta-GGA, and hybrid. There is also the possibility to include van der Waals corrections or an on-site Coulomb repulsion using DFT+U on top of another functional. More details on the different types of approximations available in VASP and how to use them can be found in the pages and subcategories listed below.

How to

References

  1. P. Hohenberg and W. Kohn, Phys. Rev. 136, B864 (1964).
  2. W. Kohn and L. J. Sham, Phys. Rev. 140, A1133 (1965).
  3. https://libxc.gitlab.io/functionals/
  4. S. Grimme, J. Comput. Chem. 27, 1787 (2006).
  5. S. Grimme, J. Antony, S. Ehrlich, and S. Krieg, J. Chem. Phys. 132, 154104 (2010).
  6. S. Grimme, S. Ehrlich, and L. Goerigk, J. Comput. Chem. 32, 1456 (2011).
  7. E. Caldeweyher, S. Ehlert, A. Hansen, H. Neugebauer, S. Spicher, C. Bannwarth, and S. Grimme, J. Chem. Phys. 150, 154122 (2019).
  8. A. Tkatchenko and M. Scheffler, Phys. Rev. Lett. 102, 073005 (2009).
  9. T. Bučko, S. Lebègue, J. Hafner, and J. G. Ángyán, J. Chem. Theory Comput. 9, 4293 (2013)
  10. T. Bučko, S. Lebègue, J. G. Ángyán, and J. Hafner, J. Chem. Phys. 141, 034114 (2014).
  11. a b A. Tkatchenko, R. A. DiStasio, Jr., R. Car, and M. Scheffler, Phys. Rev. Lett. 108, 236402 (2012).
  12. A. Ambrosetti, A. M. Reilly, and R. A. DiStasio Jr., J. Chem. Phys. 140, 018A508 (2014).
  13. T. Gould and T. Bučko, C6 Coefficients and Dipole Polarizabilities for All Atoms and Many Ions in Rows 1–6 of the Periodic Table, J. Chem. Theory Comput. 12, 3603 (2016).
  14. T. Gould, S. Lebègue, J. G. Ángyán, and T. Bučko, A Fractionally Ionic Approach to Polarizability and van der Waals Many-Body Dispersion Calculations, J. Chem. Theory Comput. 12, 5920 (2016).
  15. https://libmbd.github.io/
  16. https://github.com/libmbd/libmbd
  17. J. Hermann, M. Stöhr, S. Góger, S. Chaudhuri, B. Aradi, R. J. Maurer, and A. Tkatchenko, libMBD: A general-purpose package for scalable quantum many-body dispersion calculations, J. Chem. Phys. 159, 174802 (2023).
  18. S. N. Steinmann and C. Corminboeuf, J. Chem. Phys. 134, 044117 (2011).
  19. S. N. Steinmann and C. Corminboeuf, J. Chem. Theory Comput. 7, 3567 (2011).
  20. H. Kim, J.-M. Choi, and W. A. Goddard, III, J. Phys. Chem. Lett. 3, 360 (2012).

Subcategories

This category has the following 5 subcategories, out of 5 total.

Pages in category "Exchange-correlation functionals"

The following 118 pages are in this category, out of 118 total.